A number of experiments in this course rely on radioactive materials as sources of photons of known energy. One of the skills we hope you develop in this course is the ability to read a nuclear decay scheme and identify the elements released in that decay – which may include electrons, positrons, and/or gamma particles (high energy photons) – as well as the relative intensities of each.
Decay schemes provided here come from the following sources (noted beside each figure):
Additional information (e.g. X-ray lines, lifetimes) can be found from the online Radioactive Table of Isotopes maintained by the International Atomic Energy Agency as an interactive table at https://www-nds.iaea.org/relnsd/vcharthtml/VChartHTML.html or as a static table at https://www-nds.iaea.org/xgamma_standards/genergies1.htm.
Annotated decay scheme for Sodium-22. Note that decay schemes are published in black and white; the scheme above has been color-coded to highlight the different features that are present. |
Horizontal lines [purple] represent energy levels and are arranged so that higher energy states are placed above lower energy states. (Note that separations are not, in general, to scale.) The value written next to a horizontal line [teal] is the energy of that state, usually in MeV, relative to the lowermost energy state in the diagram. The lowermost (ground) state is at zero energy and is the stable, final state of the decay.
Some energy levels may also have an indicated lifetime [red]. If no lifetime is given, it is usually safe to assume that the decay from that state to a lower energy is nearly instantaneous.
Diagonal lines [green] represent decay processes which take one nuclear species to another (e.g. ${}^{22}_{11}\textrm{Na}$ to ${}^{22}_{10}\textrm{Ne}$ ). Possible processes include the following:
Vertical lines [orange] represent transitions from a higher nuclear energy state to a lower nuclear energy state. In most cases, a gamma ray (high energy photon) is emitted carrying away the difference in energy. These emissions are analogous to the more familiar photons emitted when electrons transition among energy levels, but the energy scales are typically much bigger.
Multiple possible transitions: In elements with multiple excited energy states, there may be multiple possible decays. In these instances, each vertical transition is labeled with a relative probability and an energy.
For example, looking at the cobalt-60 decay, the nickel nucleus can transition from the 2.158 MeV state to either the 1.3325 MeV excited state or the ground state. However, the transition to the 1.3325 MeV state is over ten times more likely (as indicated by the prefixes). Thus, we should expect to see substantially more 830 keV gammas than 2.158 MeV gammas.
Some nuclei can also undergo a process called internal conversion (IC) where the excited nucleus gives its excess energy directly to an electron, liberating that electron from its shell and sending it off with some extra kinetic energy. IC is possible only in high Z nuclei (where the electron binding energy is comparable to the excited energy of the nucleus) and only from metastable states (where the lifetime for the normal photon emission is quite long, giving enough time for the probability for an electron's wavefunction to overlap with the nucleus' wavefunction to become non-negligible).
Decay schemes also contain information about nuclear excitation states, Q values, and ln(ft) values that are not commonly used in this course.
Sodium-22 ($\tau$ = 2.6 years) decays either via electron capture or $\beta^+$ (positron) emission to an excited state of neon-22. The decay from this excited state releases an E = 1.2746 MeV photon. Note, however, that the positron created in the decay is short-lived. Once it is slowed by Coulomb interactions, it can bind with an electron to form positronium before eventually annihilating, converting all mass into energy. The most likely product of this annihilation is two back-to-back photons each of energy 511 keV, though decays of 3 or more photons are possible.
Aluminum-28 is a short-lived ($\tau$ = 2.31 minutes) isotope produced by bombarding aluminum-27 with thermal neutrons. It decays via $\beta^-$ (electron) emission to an excited state of silicon-28 and the decay from this excited state releases an E = 1.780 MeV photon.
Cobalt-57 ($\tau$ = 272 days) decays via electron capture to an excited state of iron-57. The vacancy left in the electron orbital will be filled by an electron in a higher shell, releasing a $K_\alpha$ photon of E = 6.4 keV. The excited Fe-57 will decay either by emitting a single photon of E = 137 keV or by two photons of energies E = 122 keV and E = 14.4 keV.
Cobalt-60 ($\tau$ = 1925 days) decays via $\beta^-$ (electron) emission into an excited state of nickel-60. In the relaxation to ground, the nucleus emits two photons, E = 1.1732 MeV and E = 1.3325 MeV in rapid succession. (The lifetime of the intermediate state (1.3325 MeV above ground) is 0.7 ps.)
Indium-116 is a short-lived ($\tau$ = 54.0 m) isotope of indium produced by bombarding indium-115 (weakly radioactive, $\tau$ = 4.41 x 1014 years) with thermal neutrons. It decays via $\beta^-$ (electron) emission to tin-116. The relaxation to ground can produce more than a half-dozen different photons, the most likely of which are E = 1.0972 MeV and 1.2933 MeV.
Barium-133 ($\tau$ = 10.52 years) decays via electron capture to cesium-133. The vacancy left in the electron orbital will be filled by an electron in a higher shell, releasing a $K_\alpha$ photon of E = 31 keV. The decay of the excited Cs-133 can proceed by many paths, but the two most prominent photons emitted are E = 356 keV and E = 81 keV. Notably, gammas at E = 276, 302, and 382 keV will be detectable around (and may overlap with) the 356 keV peak.
Cesium-137 ( $\tau$ = 30.04 years) decays via $\beta^-$ (electron) emission to either the ground state of barium-137 (6%) or a metastable excited state, barium-137m (94%, $\tau$ = 2.6 minutes). The metastable state decays to the stable ground state primarily by the emission of a single photon with E = 662 keV. However, due to the long life of the metastable state, there is a small chance that the nucleus will undergo an internal conversion whereby the excess energy is used to liberate a K-shell or L-shell electron. This ejection is accompanied by an X-ray as an electron from an upper energy level falls into the vacancy and releases a photon. Several photons are possible depending on the electron ($K_\alpha$ ,$K_\beta$ ,$L_\alpha$ , etc.), but the most likely photon is the $K_\alpha$ X-ray, E = 32.2 keV.
Europium-152 ($\tau$ = 19.52 y) decays via either electron capture or $\beta^+$ (positron) emission to samarium-152, or via $\beta^-$ (electron) emission to gadolinium-152. Many (many!) potential gammas are released, including samarium $K_\alpha$ x-rays. The full decay scheme is located below, but it may be more useful to use a look-up table of known emission gammas like that provided by Spectrum Techniques or the Lawrence Berkley National Laboratory Nuclide Database.
Bismuth-207 ($\tau$ = 31.55 y) decays via electron capture to lead-207. The vacancy left in the electron orbital will be filled by an electron in a higher shell, with the most likely X-ray emissions being $K_\alpha$ photons of E = 72.8 keV and 75.0 keV. The three most prominent photons emitted in the decay to ground of the excited Pb-207 are E = 569.6 keV, 1.0634 MeV and 1.7697 MeV.
Americium-241 ($\tau$ = 623 y) decays via α emission to neptunium-237. The mostly likely path leaves the neptunium in an excited state, which relaxes to the ground state and emits an x-ray of energy E = 59.54 keV. The emitted $\alpha$ -particle typically has E = 5.5 MeV, but will be rapidly stopped by the Coulomb interaction and will not penetrate very far.